Metal-induced Coordination Networks Using a C_(2v)-based Hexacarboxylate Ligand:Syntheses, Structures and Properties

【Author】

WAN Xiu-Yan;ZHANG Guang-Lu;CHEN Lian;JIANG Fei-Long;HONG Mao-Chun;College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;

【Institution】

College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Shandong Normal University;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;

【Abstract】

Metal-organic frameworks(MOFs), consisting of metal, anion and organic ligands, have attracted much attention. The structure of MOFs is affected by various factors. To explore the effects of metal ions, we synthesized six complexes, namely {[Me_2NH_2][Zn_4(H_2L)(L)]·2 H_2O·2 DMF}_n(1), {[Me_2NH_2]_2[Cd_2(L)]·2H_2O}_n(2), {[Me_2NH_2]_2[Ca_3(L)(μ-OH)_2(DMF)_2]·2H_2O}_n(3) and {[Me_2NH_2]_2[M_2(L)(μ-OH)]· H_2O·2DMF}_n(M = Co, 4; Ni, 5; Mn, 6), from a C_(2v)-based hexacarboxylate ligand([1,1';4',1'']terphenyl-3,5,2',5',3'',5''-hexacarboxylic acid(H_6L)) using metal-induced strategy. These MOFs were thoroughly characterized by single-crystal and X-ray diffraction, elemental analysis, Fourier-transform infrared spectra(FTIR) and photoluminescence.

【Keywords】

metal-induced;;syntheses;;structures;;photoluminescence properties

References

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Springer Journals Database

Total: 2 articles

  • [1] YE Cheng-Cheng a ZHU Cheng-Feng b GONG Teng-Fei a SHENG En-Hong a XUAN Wei-Min b CUI Yong b LIU Bai-Zhan c a (College of Chemistry and Materials Science, Anhui Normal University, Wuhu, Anhui 241000, China) b (School of Chemistry and Chemical Technology and State Key Laboratory of Metal Matrix Composites, Shanghai Jiaotong University, Shanghai 200240, China) c (China Tobacco, Shanghai 200240, China), A Novel Cu-based Metallosalan Complex: Synthesis, Structure and Chiral Sensor Study, Chinese Journal of Structural Chemistry,
  • [2] Bin Li;;Hui‐Min Wen;;Yuanjing Cui;;Wei Zhou;;Guodong Qian;;Banglin Chen, Emerging Multifunctional Metal–Organic Framework Materials, Advanced Materials,

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