Synthesis, Structure and Luminescent Properties of a Nine-Coordinated Praseodymium Complex


Sun Lining Zhang Hongjie~*, Fu Lianshe, Liu FengyiMeng Qingguo, Peng Chunyun, Yu Jiangbo Wang Shubin(Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China)


The Pr(TTA)_3phen(C_2H_5OH)quarternary complex with 2-thenoyltrifluoro-acetone(TTA), 1,10-phenanthroline(phen)and ethanol were synthesized and characterized by single-crystal X-ray diffraction. The central Pr~(3+) ion is nine-coordinated. The infrared(IR)spectrum, diffuse reflectance(DR)spectrum and fluorescence measurements of the complex were investigated.


praseodymium complex; crystal structure; luminescence,rare earths


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Total: 13 articles

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