Preparation and Characterization of Hybrid Luminescence Mesoporous MCM-48 Doped with Eu(Ⅲ) Complex


Meng Qingguo, Li Huanrong, Peng Chunyun, Zhang Hongjie Boutinaud P,Franville A C, Mahiou R (Key Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 , China;Laboratoire des Materiaux Inorganiques, UMR CNRS 6002 , Univer-site Blaise-Pascal et ENSCCF, 24 Avenue des Landau, F-63177 Aubiere Cedex, France)


<正> The preparation of hybrid mesoporous MCM-48 grafted by vinyl group via post-grafting process was reported and studied by X-ray diffraction, BET and 29Si solid MAS NMR. An organic β-diketonate Europium complex Eu(DBM)3·2H2O complex was introduced into the hybrid MCM-48 host by a simple wet impregnation method, and the corresponding luminescence property was characterized.


mesoporous; hybrid materials; rare earths


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