A Stable Polyoxometalate-based Coordination Polymer for Light Driven Degradation of Organic Dye Pollutant

【Author】

WANG Man;WU Xiao-Yuan;WANG Sa-Sa;LU Can-Zhong;College of Chemistry,Fuzhou University;CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences;University of Chinese Academy of Sciences;Xiamen Institute of Rare Earth Materials,Chinese Academy of Sciences;

【Institution】

College of Chemistry,Fuzhou University;CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences;University of Chinese Academy of Sciences;Xiamen Institute of Rare Earth Materials,Chinese Academy of Sciences;

【Abstract】

A new POM-based coordination polymer,[Cl_2Cu~I_(11)(trz)_8][H_3SiW_(12)O_(40)](1),was successfully obtained under hydrothermal reaction.The compound was characterized by single-crystal X-ray diffraction,TGanalyses,IR spectra and PXRD analysis.Compound 1 shows extreme stability and outstanding catalytic activity to the degradation of organic dye pollutant.

【Keywords】

polyoxometalate-based coordination polymer;;photocatalysis;;1,2,4-triazole

References

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Springer Journals Database

Total: 25 articles

  • [1] Yamase Toshihiro, Photo- and Electrochromism of Polyoxometalates and Related Materials., Chemical reviews,
  • [2] Rhule Jeffrey T.;;Hill Craig L.;;Judd Deborah A.;;Schinazi Raymond F., Polyoxometalates in Medicine., Chemical reviews,
  • [3] Aldamen Murad A;;Clemente-Juan Juan M;;Coronado Eugenio;;Martí-Gastaldo Carlos;;Gaita-Ari?o Alejandro, Mononuclear lanthanide single-molecule magnets based on polyoxometalates., Journal of the American Chemical Society,
  • [4] Reinoso S;Vitoria P;San Felices L;Montero A;Lezama L;Gutierrez-Zorrilla JM, Tetrahydroxy-p-benzoquinone as a source of polydentate O-donor ligands. Synthesis, crystal structure, and magnetic properties of the [Cu( bpy)(dhmal)](2) dimer and the two-dimensional [{SiW12O40}{Cu-2(bpy) (2)(H2O)(ox)(2, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,

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