A Linear Ce~Ⅲ Complex Based on in-situ Generated N-hydroxy-1,8-naphthalenedicarboximide

【Author】

LIU Yang;CAO Xue-Li;WANG Wei;LI Guo-Ling;LI Shun;HUANG You-Gui;College of Chemistry,Fuzhou University;CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences;Xiamen Institute of Rare Earth Materials,Haixi Institutes,Chinese Academy of Sciences;

【Institution】

College of Chemistry,Fuzhou University;CAS Key Laboratory of Design and Assembly of Functional Nanostructures,and Fujian Provincial Key Laboratory of Nanomaterials,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences;Xiamen Institute of Rare Earth Materials,Haixi Institutes,Chinese Academy of Sciences;

【Abstract】

A Ce~(Ⅲ) linear complex of N-hydroxy-1,8-naphthalenedicarboximide (HL) has been synthesized with acenaphthoquinone dioxime (acndH_2) under solvothermal conditions,in which L is generated by a series of in-situ reactions starting from acndH_2.X-ray crystallography reveals the coordination chains of Ce~(Ⅲ) ions are assembled into a 3D supramolecular framework viaπ···πinteractions.The title complex has been characterized by IR and UV-Vis spectra and thermogravimetric analysis (TGA).Furthermore,the fluorescent properties study demonstrated a ligand-based emission of the Ce~(Ⅲ) complex with~6 nm blue-shift compared with the emisision of the HL ligand.

【Keywords】

N-hydroxy-1,8-naphthalenedicarboximide;;acenaphthoquinone dioxime;;rare earth;;fluorescence complex;;X-ray crystallography

References

To explore the background and basis of the node document

Springer Journals Database

Total: 25 articles

  • [1] Shen,Baoxing;Qian,Ying;School of Chemistry and Chemical Engineering,Southeast University;, A Novel Fluorescent Dye Naphthalene Imide-Fluorine Boron Two Pyrrole: Synthesis, Fluorescence Resonance Energy Transfer and Cell Imaging, Chinese Journal of Organic Chemistry,
  • [2] WEI Chen;MA Li;WEI HuiBo;LIU ZhiWei;BIAN ZuQiang;HUANG ChunHui;Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University;, Advances in luminescent lanthanide complexes and applications, Science China(Technological Sciences),
  • [3] You-Gui Huang;;Fei-Long Jiang;;Da-Qiang Yuan;;Min-Yan Wu;;Qiang Gao;;Wei Wei;;Mao-Chun Hong, Intricate 3D lanthanide–organic frameworks with mixed nodes nets, Journal of Solid State Chemistry,
  • [4] You-Gui Huang;;Fei-Long Jiang;;Mao-Chun Hong, Magnetic lanthanide–transition-metal organic–inorganic hybrid materials: From discrete clusters to extended frameworks, Coordination Chemistry Reviews,

More>>

Similar documents

Documents that have the similar content to the node document

  • [1] Hydrothermal synthesis and crystal structure of copper (II)coordination polymer composed of helix-like chains:[Cu(NIPH)(bpy)], Chinese Science Bulletin, 2006 (14)
  • [2] Tisato Kajiyama,Daisuke Kawaguchi,Keiji Tanaka, POLYMER CHAIN DIFFUSION AT A TEMPERATURE BELOW ITS BULK GLASS TRANSITION TEMPERATURE, Chinese Journal of Polymer Science, 2003 (02)
  • [3] SYNTHESIS AND CHARACTERIZATION OF A NEW THREE-ARMS-NINE-CHAINS DISCOTIC LIQUID CRYSTAL, Chinese Chemical Letters, 1992 (08)
  • [4] RATE OF INTRA-MOLECULAR CONTACT FORMATION IN SHORT TWO-DIMENSIONAL COMPACT POLYMERS CHAINS, Chinese Journal of Polymer Science, 2006 (01)

More>>