Chang-Pu Wan;Jun-Dong Yi;Rong Cao;Yuan-Biao Huang;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;University of Chinese Academy of Sciences;School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China;Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China;
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;University of Chinese Academy of Sciences;School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China;Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China;
Porous crystalline metal-organic frameworks(MOFs) and covalent organic frameworks(COFs) are promising platforms for electrocatalytic reduction of CO_2(CO_2RR) due to their large CO_2 adsorption uptakes and periodically arranged single active sites. However, the applications in CO_2RR of the traditional MOFs and COFs are greatly limited by their low electron conductivity. In recent years, numerous types of MOFs and COFs with high intrinsic conductivity have been rationally designed and successfully constructed, and some of them have been applied in CO_2RR. In this review, the applications of conductive MOFs and COFs in CO_2RR have been summarized. The conductive MOFs and COFs can be categorized according to the methods, in which the conductivity is enhanced, such as constructing fully π-conjugated backbones,donor-acceptor heterojunction, enhancing the π-π stacking interactions between organic moieties and/or the introduction of guest molecules.
metal-organic frameworks;;covalent organic frameworks;;CO_2 electroreduction reaction;;conductive frameworks
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