Conductive Metal/Covalent Organic Frameworks for CO_2 Electroreduction

【Author】

Chang-Pu Wan;Jun-Dong Yi;Rong Cao;Yuan-Biao Huang;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;University of Chinese Academy of Sciences;School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China;Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China;

【Institution】

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;University of Chinese Academy of Sciences;School of Chemistry and Materials Science, Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), University of Science and Technology of China;Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China;

【Abstract】

Porous crystalline metal-organic frameworks(MOFs) and covalent organic frameworks(COFs) are promising platforms for electrocatalytic reduction of CO_2(CO_2RR) due to their large CO_2 adsorption uptakes and periodically arranged single active sites. However, the applications in CO_2RR of the traditional MOFs and COFs are greatly limited by their low electron conductivity. In recent years, numerous types of MOFs and COFs with high intrinsic conductivity have been rationally designed and successfully constructed, and some of them have been applied in CO_2RR. In this review, the applications of conductive MOFs and COFs in CO_2RR have been summarized. The conductive MOFs and COFs can be categorized according to the methods, in which the conductivity is enhanced, such as constructing fully π-conjugated backbones,donor-acceptor heterojunction, enhancing the π-π stacking interactions between organic moieties and/or the introduction of guest molecules.

【Keywords】

metal-organic frameworks;;covalent organic frameworks;;CO_2 electroreduction reaction;;conductive frameworks

References

To explore the background and basis of the node document

Springer Journals Database

Total: 56 articles

  • [1] YE Ke;WANG Guo-Xiong;BAO Xin-He;State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences;Key Laboratory of Superlight Materials and Surface Technology of Ministry of Education, College of Materials Science and Chemical Engineering, Harbin Engineering University;, Electrodeposited Sn-based Catalysts for CO_2 Electroreduction, Chinese Journal of Structural Chemistry,
  • [2] CUI Pei-Pei;LIU Yong;ZHAI Hong-Guo;ZHU Jian-Peng;YAN Wen-Ning;YANG Yun-Min;Shandong Provincial Key Laboratory of Functional Macromolecular Biophysics, Shandong Universities Key Laboratory of Functional Biological Resources Utilization and Development, School of Life Science, Dezhou University;Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing National Laboratory of Microstructures, Nanjing University;School of Mechanical and Electronical Engineering, Dezhou University;, Two Copper-organic Frameworks Constructed from the Flexible Dicarboxylic Ligands, Chinese Journal of Structural Chemistry,
  • [3] Shasha Zheng;Qing Li;Huaiguo Xue;Huan Pang;Qiang Xu;School of Chemistry and Chemical Engineering, and Institute for Innovative Materials and Energy, Yangzhou University;AIST-Kyoto University Chemical Energy Materials Open Innovation Laboratory, National Institute of Advanced Industrial Science and Technology;, A highly alkaline-stable metal oxide@metal–organic framework composite for high-performance electrochemical energy storage, National Science Review,
  • [4] HOU Shi-Sheng;XU Ze-Tong;ZHANG You-Kai;XIE Kui;GAN Li-Zhen;College of Transportation and Civil Engineering, Fujian Agriculture and Forestry University;Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences;, Enhanced CO_2 Electrolysis with Mn-doped SrFeO_(3-δ) Cathode, Chinese Journal of Structural Chemistry,

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