Selective Electrocatalytic Hydrogenation of 5-Hydroxymethylfurfural to 2,5-Dihydroxymethylfuran on Bimetallic PdCu Alloy

【Author】

Xu Yue;Weixing Zhao;Shuangyin Wang;Yuqin Zou;State Key Laboratory of Chem/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University;Shenzhen Institute of Hunan University;

【Institution】

State Key Laboratory of Chem/Bio-Sensing and Chemometrics, College of Chemistry and Chemical Engineering, Advanced Catalytic Engineering Research Center of the Ministry of Education, Hunan University;Shenzhen Institute of Hunan University;

【Abstract】

2,5-dihydroxymethylfuran(DHMF), obtained from 5-hydroxymethylfurfural(HMF) by electrochemical method, is a promising building block for polymers. However,one challenge of this process is to reduce initial potential and improve catalytic selectivity. In this work, the PdCu bimetallic catalyst is prepared with an onset potential of -0.05 VRHE and a selectivity of 99%. Compared with the single Cu electrocatalyst, the adsorption of HMF and proton is improved by introducing of Pd, which is demonstrated by the electrochemical results and hydrogen production rate. This work provides an effective strategy to improve the selectivity of Cu-based electrocatalyst and builds a relationship between the adsorption capacity and the electrocatalytic performance.

【Keywords】

biomass;;2,5-dihydroxymethylfuran;;electrocatalyst;;bimetallic alloy;;hydrogenation

References

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Total: 35 articles

  • [1] Fuzhi Li;Jingsha Li;Qiuju Feng;Jun Yan;Yougen Tang;Haiyan Wang;College of Chemistry and Chemical Engineering,Central South University;College of Life Sciences and Chemistry,Hunan University of Technology;College of Chemistry and Chemical Engineering,Jishou University;Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources,Central South University;, Significantly enhanced oxygen reduction activity of Cu/CuN_xC_y co-decorated ketjenblack catalyst for Al–air batteries, Journal of Energy Chemistry,
  • [2] Ling Zhou;Xiaorong Zhu;Hui Su;Hongzhen Lin;Yanhong Lyu;Xu Zhao;Chen Chen;Nana Zhang;Chao Xie;Yingying Li;Yuxuan Lu;Jianyun Zheng;Benrt Johannessen;San Ping Jiang;Qinghua Liu;Yafei Li;Yuqin Zou;Shuangyin Wang;State Key Laboratory of Chem/Bio-Sensing and Chemometrics,Provincial Hunan Key Laboratory for Graphene Materials and Devices,College of Chemistry and Chemical Engineering,the National Supercomputer Centers in Changsha,Hunan University;College of Chemistry and Materials Science,Nanjing Normal University;National Synchrotron Radiation Laboratory,University of Science and Technology of China;i-LAB,Suzhou Institute of Nano-Tech and Nano-Bionics (SINANO),Chinese Academy of Sciences;Department of Educational Science,Hunan First Normal University;Australian Synchrotron;Western Australian School of Mines: Minerals,Energy and Chemical Engineering and Fuels and Energy Technology Institute,Curtin University;, Identification of the hydrogen utilization pathway for the electrocatalytic hydrogenation of phenol, Science China(Chemistry),
  • [3] Ajit SinghMamman;Jong‐MinLee;Yeong‐CheolKim;In TaekHwang;No‐JoongPark;Young KyuHwang;Jong‐SanChang;Jin‐SooHwang, Furfural: Hemicellulose/xylosederived biochemical, Biofuels, Bioprod. Bioref.,
  • [4]

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