Metal-induced C-H/B-H Bond Activation:Reactions of a 16-electron CpCo Half-sandwich Complex with Organic Molecules

【Author】

ZHANG Rui and YAN Hong~* State Key Laboratory of Coordination Chemistry,School of Chemistry and Chemical Engineering, Nanjing University,Nanjing,JiangSu 210093,China

【Abstract】

<正>The reaction chemistries of the 16-electron half-sandwich complexes Cp'M(E_2C_2B_(10)H_(10))(Cp'=η~5-C_5H_5,η~5-C_5Me_5,η~5-1,3-~tBu_2C_5H_3;M=Co,Rh,Ir;E=S,Se)and(p-cymene)M(E_2C_2B_(10)H_(10))(M= Ru,Os;E=S,Se)containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dichalcogenolate ligand with alkynes have got fruitful results.We have researched the reaction between

【Keywords】

B-H/C-H bond activation;;carborane;;transition metal;;alkyne

References

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Springer Journals Database

Total: 2 articles

  • [1] Herberhold Max;Yan Hong;Milius Wolfgang;Wrackmeyer Bernd, Rhodium-Induced Selective B (3)/B (6)-Disubstitution of ortho-Carborane-1,2-dithiolate, Angew.Chem.Int.Ed, Angewandte Chemie International Edition (Angewandte Chemie International Edition)
  • [2] Xu Bao-Hua;Tao Jing-Cong;Li Yi-Zhi;Li Shu-Hua;Yan Hong, Metal-Induced B-H Bond Activation:Addition of Methyl Acetylene Monocarboxylate to CpCo Half-Sandwich Complexes Containing a Chelating 1,2-Dicarba-closo-dodecaborane-1,2-dichalcogenolate Ligand, Organometallics, Organometallics (Organometallics)

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